Скачать или смотреть Real gas | Wikipedia audio article

This is an audio version of the Wikipedia Article:
https://en.wikipedia.org/wiki/Real_gas


00:00:56 1 Models
00:01:05 1.1 Van der Waals model
00:04:19 1.2 Redlich–Kwong model
00:08:37 1.3 Berthelot and modified Berthelot model
00:10:23 1.4 Dieterici model
00:12:02 1.5 Clausius model
00:14:15 1.6 Virial model
00:16:14 1.7 Peng–Robinson model
00:17:22 1.8 Wohl model
00:24:03 1.9 Beattie–Bridgeman model
00:25:48 1.10 Benedict–Webb–Rubin model
00:27:35 2 Thermodynamic expansion work
00:28:07 3 See also



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SUMMARY
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Real gases are non-hypothetical gases whose molecules occupy space and have interactions; consequently, they adhere to gas laws.
To understand the behaviour of real gases, the following must be taken into account:

compressibility effects;
variable specific heat capacity;
van der Waals forces;
non-equilibrium thermodynamic effects;
issues with molecular dissociation and elementary reactions with variable compositionFor most applications, such a detailed analysis is unnecessary, and the ideal gas approximation can be used with reasonable accuracy. On the other hand, real-gas models have to be used near the condensation point of gases, near critical points, at very high pressures, to explain the Joule–Thomson effect and in other less usual cases. The deviation from ideality can be described by the compressibility factor Z.