Скачать или смотреть Osmium Tetroxide Dihydroxylation | OsO4 Mechanism | Organic Chemistry | Practice Problems

Osmium tetroxide is an osmium coordination entity consisting of four oxygen atoms bound to a central osmium atom via covalent double bonds. It has a role as an oxidizing agent, a poison, a fixative and a histological dye.

Osmium oxide forms monoclinic crystals. It has a characteristic acrid chlorine-like odor. The element name osmium is derived from osme, Greek for odor. OsO4 is volatile: it sublimes at room temperature. It is soluble in a wide range of organic solvents. It is also moderately soluble in water, with which it reacts reversibly to form osmic acid . Pure osmium oxide is probably colourless and it has been suggested that its yellow hue is due to osmium dioxide (OsO2) impurities. The osmium tetroxide molecule is tetrahedral and therefore non-polar. This nonpolarity helps OsO4 penetrate charged cell membranes. OsO4 is 518 times more soluble in carbon tetrachloride than in water.

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