Скачать или смотреть How do solvents direct SN1 vs SN2 reactions?

Solvent Effects on SN1 and SN2 Reactions

1. Protic solvents surround charged particles
2. Stabilize ionic intermediates
3. Favor unimolecular pathways
4. Aprotic solvents leave nucleophiles free
5. Favor bimolecular substitution
6. Solvent polarity and H-bonding matter

Common Solvent Mistakes in Organic Reactions

1. Assuming solvent only affects rate
2. Confusing polarity with hydrogen bonding
3. Believing aprotic means nonpolar

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