Hash oil or cannabis oil is an oleoresin obtained by the extraction of cannabis or hashish. It is a cannabis concentrate containing many of its resins and terpenes – in particular, tetrahydrocannabinol (THC), cannabidiol (CBD), and other cannabinoids. Hash oil is usually consumed by smoking, vaporizing or eating. Preparations of hash oil may be solid or colloidal depending on both production method and temperature and are usually identified by their appearance or characteristics. Color most commonly ranges from transparent golden or light brown, to tan or black. There are various extraction methods, most involving a solvent, such as butane or ethanol.
Hash oil is an extracted cannabis product that may use any part of the plant, with minimal or no residual solvent. It is generally thought to be indistinct from traditional hashish, according to the 1961 UN Single Convention on Narcotic Drugs (Schedule I and IV), as it is "the separated resin, whether crude or purified, obtained from the cannabis plant".
Hash oil may be sold in cartridges used with pen vaporizers. Cannabis retailers in California have reported about 40% of their sales are from cannabis oils.[1]
Composition
The tetrahydrocannabinol (THC) content of hash oil varies tremendously, since the manufacturers use a varying assortment of marijuana plants and preparation techniques. Dealers sometimes cut hash oils with other oils.[2][3] The form of the extract varies depending on the extraction process used; it may be liquid, a clear amber solid (called “shatter"), a sticky semisolid substance (called "wax"), or a brittle honeycombed solid (called "honeycomb wax").[4]
Hash oil seized in the 1970s had a THC content ranging from 10% to 30%. The oil available on the U.S. West Coast in 1974 averaged about 15% THC.[2] Samples seized across the United States by the Drug Enforcement Administration over an 18-year period (1980–1997) showed that THC content in hashish and hashish oil averaging 12.9% and 17.4%, respectively, did not show an increase over time.[5] The highest THC concentrations measured were 52.9% in hashish and 47.0% in hash oil.[6] Hash oils in use in the 2010s had THC concentrations as high as 90%[7][8] and other products achieving higher concentrations [9] Following an outbreak of vaping related pulmonary illnesses and deaths in 2019 NBC News conducted tests on different black market THC vape cartridges and found cartridges containing up to 30% Vitamin E acetate and trace amounts of fungicides and pesticides that may be harmful.[10]
The following compounds were found in naphtha extracts of Bedrocan Dutch medical cannabis:[11]
Cannabinoids: THC (~ 30%) and THCA (~ 60%).
Monoterpenes (~ 5%): β-pinene, myrcene, β-phellandrene, cis-ocimene, terpinolene, and terpineol.
Sesquiterpenes (~ 5%): β-caryophyllene, humulene, δ-guaiene, γ-cadinene, eudesma-3,7(11)-diene, and elemene.
Solvent-derived/hydrocarbon extracts
Hash oil is produced by solvent extraction (maceration, infusion or percolation) of marijuana or hashish. After filtering and evaporating the solvent, a sticky resinous liquid with a strong herbal odor (remarkably different from the odor of hemp) remains.[2][18]
Fresh, undried plant material is less suited for hash oil production, because much THC and CBD will be present in their carboxylic acid forms (THCA and CBDA), which may not be highly soluble in some solvents.[2] The acids are decarboxylated during drying and heating (smoking).
A wide variety of solvents can be used for extraction, such as chloroform, dichloromethane, petroleum ether, naphtha, benzene, butane, methanol, ethanol, isopropanol, and olive oil.[2][11] Currently, resinoids are often obtained by extraction with supercritical carbon dioxide. The alcohols extract undesirable water-soluble substances such as chlorophyll and sugars (which can be removed later by washing with water). Non-polar solvents such as benzene, chloroform and petroleum ether will not extract the water-soluble constituents of marijuana or hashish while still producing hash oil. In general, non-polar cannabis extracts taste much better than polar extracts. Alkali washing further improves the odor and taste.
Hash oil produced using a hydrocarbon like butane in California, referred to as shatter, due to its very thick and glass-like consistency
The oil may be further refined by 1) alkali washing, or removing the heavy aromatic carboxylic acids with antibiotic properties, which may cause heartburn, gallbladder and pancreas irritation, and resistance to hemp antibiotics; 2) conversion of CBD to THC.
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