Thermodynamics and Chemical Dynamics 131C. Lecture 26. Transition State Theory

UCI Chem 131C Thermodynamics and Chemical Dynamics (Spring 2012)
Lec 26. Thermodynamics and Chemical Dynamics -- Transition State Theory --
View the complete course: http://ocw.uci.edu/courses/chem_131c_...
Instructor: Reginald Penner, Ph.D.

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Description: In Chemistry 131C, students will study how to calculate macroscopic chemical properties of systems. This course will build on the microscopic understanding (Chemical Physics) to reinforce and expand your understanding of the basic thermo-chemistry concepts from General Chemistry (Physical Chemistry.) We then go on to study how chemical reaction rates are measured and calculated from molecular properties. Topics covered include: Energy, entropy, and the thermodynamic potentials; Chemical equilibrium; and Chemical kinetics.

Thermodynamics and Chemical Dynamics (Chem 131C) is part of OpenChem: http://ocw.uci.edu/openchem/
This video is part of a 27-lecture undergraduate-level course titled "Thermodynamics and Chemical Dynamics" taught at UC Irvine by Professor Reginald M. Penner.

Recorded June 6, 2012.

Index of Topics:
0:02:54 Where Does the Arrhenius Equation Come From?
0:04:34 Transition State Theory
0:11:16 Activated Complex
0:14:30 Equilibrium Constants from Partition Functions
0:23:25 Calculating the Partition Function
0:26:28 Vibration Along the Reaction Coordinate
0:32:06 The Eyring Equation
0:35:38 Calculating the Pre-Exponential Factor in the Arrhenius Equation
0:39:27 Activities
0:40:26 Debye-Huckel Limiting Law
0:42:02 Thermodynamic Constant
0:47:25 Equation for the Kinetic Salt Effect

Required attribution: Penner, Reginald Thermodynamics and Chemical Dynamics 131C (UCI OpenCourseWare: University of California, Irvine), http://ocw.uci.edu/courses/chem_131c_.... [Access date]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (http://creativecommons.org/licenses/b....