27.05 Linear Free-energy Relations: Applying Hammett Constants

Описание к видео 27.05 Linear Free-energy Relations: Applying Hammett Constants

The Hammett constant as an independent measure of electron donating/withdrawing strength. Design and output of a Hammett study. Mechanistic interpretation of the reaction constant.

00:00 Correlating Sigma and Reaction Rate; Linear Free-energy Relations
02:27 The Hammett Plot
04:37 Hammett Study of a Reaction with Electrophilic Substrate
06:55 Hammett Study of a Reaction with Nucleophilic Substrate
08:50 "Electronic Sensitivity" from the Reaction Constant

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