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The MC (Main Character) in the anime Akame ga Kill! is Tatsumi, a young villager who joins the assassination group Night Raid to fight against the corrupt empire, although the title refers to Akame, the main heroine and expert assassin of the same group. Tatsumi is the protagonist whose story follows, while Akame serves as the central female character and Tatsumi's guardian angel.
Explanation:
Tatsumi: The central character whose story begins with his journey from the countryside to the capital, where he is recruited by Night Raid. He is the main protagonist in the anime's narrative.
Akame: The main heroine and a powerful member of Night Raid. The title "Akame ga Kill!" refers to her as the red-eyed assassin at the center of the story, but narratively, Tatsumi is the character whose story takes the greater focus.