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Finding personalities in anime:

It may be over the top, and silly, but pay attention to the plethora of different personalities. In particular pay attention to their voices and speech patterns. English Subbed; spoilers, One Piece, War of the Best:    • Видео  

For something a little different (and more subtle), check out this clip from a horror fantasy. Pay more attention to facial expressions and actions this time. Warning, en media res; spoilers, Attack on Titan, Eren's Trial:    • Видео  

A couple of resources to help you get to know your character:

Character Interview: http://blog.bizodo.com/2013/02/15-uno...

Good Personality Quiz: http://www.learnmyself.com/

Character Development Questions from Tumblr: http://oslusiadas.tumblr.com/post/127...

EDIT
Extra Credits did a great and relevant video to the topic. Check it out, and the subsequent subject matter:    • Видео