Organomolybdenum chemistry | Wikipedia audio article

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00:00:19 1 Mo(0) and more reduced states
00:01:45 2 Mo(II)
00:02:12 3 Mo(IV)
00:02:24 4 Mo(V) and Mo(VI)
00:02:34 5 Organotungsten compounds
00:02:51 6 Applications
00:02:57 7 References
00:03:08 Mo(CH3)5, Mo(CH3)6, and salts of [Mo(CH3)7]- are known.Oxo and imide (RN=) ligands are found in several high oxidation state organomolybdenum compounds. The complexes (C5R5)MoO2X are illustrative. Schrock's Mo-based olefin metathesis catalysts feature molybdenum(VI) centers supported by alkoxide, alkylidene, and imido ligands.
00:03:41 Organotungsten compounds
00:03:52 Tungsten analogues of almost all organoMo compounds are known. Some notable examples include hexamethyltungsten and analogues of Schrock olefin metathesis catalysts.
00:04:07 Applications



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SUMMARY
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Organomolybdenum chemistry is the chemistry of chemical compounds with Mo-C bonds. The heavier group 6 elements molybdenum and tungsten form organometallic compounds similar to those in organochromium chemistry but higher oxidation states tend to be more common.