[1] Metal Ligand Bonding In Transition Metal Complexes | Inorganic chemistry | BSc 3rd Year

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For Bsc 3rd year Students

In Chemistry, a metal–ligand multiple bond describes the interaction of certain ligands with a metal with a bond order greater than one.Coordination complexes featuring multiply bonded ligands are of both scholarly and practical interest. Transition metal carbene complexes catalyze the olefin metathesis reaction. 

According to the valence bond theory,

Electrons in a molecule occupy atomic orbitals rather than molecular orbitals. The atomic orbitals overlap on the bond formation and the larger the overlap the stronger the bond.

The metal bonding is essentially covalent in origin and metallic structure involves resonance of electron-pair bonds between each atom and its neighbors.
Postulates of Valence Bond Theory

The important postulates of the valence bond theory are listed below.

Covalent bonds are formed when two valence orbitals (half-filled) belonging to two different atoms overlap on each other. The electron density in the area between the two bonding atoms increases as a result of this overlapping, thereby increasing the stability of the resulting molecule.

The presence of many unpaired electrons in the valence shell of an atom enables it to form multiple bonds with other atoms. The paired electrons present in the valence shell do not take participate in the formation of chemical bonds as per the valence bond theory.

Covalent chemical bonds are directional and are also parallel to the region corresponding to the atomic orbitals that are overlapping.

Sigma bonds and pi bonds differ in the pattern that the atomic orbitals overlap in, i.e. pi bonds are formed from sidewise overlapping whereas the overlapping along the axis containing the nuclei of the two atoms leads to the formation of sigma bonds.

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part 1
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part 2
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