Lithium-rich oxides (Li-rich oxides) are promising cathode materials for next-generation lithium-ion batteries due to their high capacity and energy density. However, their practical application is hindered by structural instability, voltage decay, and oxygen release during cycling. Unlocking stability in these materials requires a multifaceted approach, including cation doping, surface modifications, and defect engineering to enhance structural robustness and mitigate undesirable phase transformations. Additionally, tuning the anionic redox activity and optimizing electrode-electrolyte interactions can further improve cycling stability and performance. By addressing these challenges, Li-rich oxides can be leveraged for more durable and high-performance energy storage solutions.
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